I've only worked in full stack and backend but I've enjoyed backend more personally. Working in the Java space on backend servers has been very interesting. Front end development was part of the full stack work I did when I first got a job in the field but it was very simple with just jQuery and some other small libraries. I will say that working on just backend projects has removed a good portion of front end thinking from my mind. I usually have to sit with a front end engineer to see how the API's I write are used. That's more of a me problem though.
But really, if you want to try out python then do it. I've used python for small scripts to run at work and in my own personal projects at home and I really enjoy it.
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